Reactions of thallium(III) chloride with (aryl)silver(I) complexes. Crystal structure of [Tl(mes)2][TlCl3(mes)] (mes = mesityl).

  1. Laguna, A. 2
  2. Fernández, E.J. 1
  3. Mendía, A. 1
  4. Ruiz-Romero, Ma.E. 1
  5. Jones, P.G.
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Braunschweig University of Technology
    info

    Braunschweig University of Technology

    Brunswick, Alemania

    ROR https://ror.org/010nsgg66

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Journal:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Year of publication: 1989

Volume: 365

Issue: 3

Pages: 201-206

Type: Article

SCOPUS: 2-s2.0-0000408602 WoS: WOS:A1989U387800002 GOOGLE SCHOLAR

More publications in: Journal of Organometallic Chemistry

Abstract

The arylsilver derivatives AgR (R = mesityl, C6F3H2, C6F5) react with TlCl3 to give arylthallium(III) complexes of the types [TlR2][TlCl3R], TlClR2 or TlR3. The structure of [Tl(mes)2][TlCl3(mes)] has been established by X-ray crystallography; it consists of linear [Tl(mes)2]+ cations and tetrahedral [TlCl3(mes)]- anions, linked into chains by additional weak Tl...Cl interactions. © 1989.