Polyhalophenylsilver(I) complexes.

  1. Fernández, E.J. 1
  2. Laguna, A. 2
  3. Mendìa, A. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

Zeitschrift:
Inorganica Chimica Acta

ISSN: 0020-1693

Datum der Publikation: 1994

Ausgabe: 223

Nummer: 1-2

Seiten: 161-164

Art: Artikel

SCOPUS: 2-s2.0-4243610820 WoS: WOS:A1994PF17300026 GOOGLE SCHOLAR

Andere Publikationen in: Inorganica Chimica Acta

Zusammenfassung

The reaction of [AgR] (R=2,4,6-C6F3H2, C6F5 or C6Cl5) with neutral ligands L (L=pyridine, 3-fluoropyridine, tetrahydrothiophene or 2,2′-bipyridyl) gives [Ag2R2L]. The same complexes are obtained by reaction of NBu4[AgR2] with [AgL2]ClO4. The 19F NMR spectra suggest the presence of bridging perfluorophenyl groups and a tetranuclear structure is proposed. © 1994.