[Tl(OPPh3)2][Au(C6F5)2]: the first extended unsupported gold-thallium linear chain

  1. Crespo, O. 2
  2. Fernández, E.J. 1
  3. Jones, P.G. 3
  4. Laguna, A. 2
  5. López-de-Luzuriaga, J.M. 1
  6. Mendía, A. 1
  7. Monge, M. 1
  8. Olmos, E. 1
  1. 1 Universidad de La Rioja
    info

    Universidad de La Rioja

    Logroño, España

    ROR https://ror.org/0553yr311

  2. 2 Instituto de Nanociencia y Materiales de Aragón
    info

    Instituto de Nanociencia y Materiales de Aragón

    Zaragoza, España

    ROR https://ror.org/031n2c920

  3. 3 Braunschweig University of Technology
    info

    Braunschweig University of Technology

    Brunswick, Alemania

    ROR https://ror.org/010nsgg66

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Revista:
Chemical Communications

ISSN: 1359-7345

Any de publicació: 1998

Volum: 20

Número: 20

Pàgines: 2233-2234

Tipus: Article

SCOPUS: 2-s2.0-21844442127 WoS: WOS:000076598700031 GOOGLE SCHOLAR

Altres publicacions en: Chemical Communications

Resum

Li[Au(C6F5)2] reacts with TlNO3 in the presence of OPPh3 affording a complex of stoichiometry [AuTl(C6F5)2-(OPPh3) 2]n, which presents different luminescence properties depending on the conditions and whose crystal structure reveals the existence of unsupported Au-Tl bonds forming a polymeric linear chain.