Estudio de la descomposición térmica de compuestos tipo hidrotalcita
- Nebot Díaz, Isaac 2
- Rives Arnau, Vicente 3
- Rocha, J. 1
- Carda Castelló, Juan Bautista 2
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1
Universidade de Aveiro
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2
Universitat Jaume I
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3
Universidad de Salamanca
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ISSN: 0366-3175
Any de publicació: 2002
Volum: 41
Número: 4
Pàgines: 411-414
Tipus: Article
Altres publicacions en: Boletín de la Sociedad Española de Cerámica y Vidrio
Resum
Thermal decomposition of hydrotalcite-like compounds with formula Mgx Al1-x(CO3 )x/2·nH2 O has been studied varying the molar ratio (x) between Mg and Al cations. Compounds synthesized by coprecipitation method at fixed pH, have been fired at different temperatures between 500 and 1200 ºC with different remaining times. This study has been carried out by Differential Thermal and Thermogravimetric Analysis (DTA/TG), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and 27Al Nuclear Magnetic Resonance (27Al-MAS-NMR) Main results show that the optimum molar ratio (x) to hydrotalcite phase formation is between 0.20 and 0.35, obtaining spinel (MgAl2 O4 ) and Periclase (MgO) as the decomposition compounds.
Informació de finançament
Asimismo, al proyecto MAT-2000-1148- C02-01 del MCyT por el apoyo económico prestado.Finançadors
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MCYT
Spain
- MAT-2000-1148- C02-01
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