Poly-N-Heterocyclic Carbene Ligands with Polyaromatic Linkers. Self-Assembly and Host-Guest Chemistry

  1. Mejuto Nieblas, Carmen
Supervised by:
  1. Eduardo Víctor Peris Fajarnés Director
  2. Gregorio Guisado Barrios Co-director

Defence university: Universitat Jaume I

Fecha de defensa: 16 June 2017

Committee:
  1. Javier A. Cabeza Chair
  2. Ana Rita Guerreiro Petronilho Secretary
  3. Dmitri Gusev Committee member
  4. Celedonio M. Álvarez Committee member

Type: Thesis

Teseo: 477799 DIALNET lock_openTDX editor

Abstract

In summary, a series of polytopic ligands based on NHC and MIC ligands have been synthesized in this Doctoral Thesis by means of different synthetic routes that gave rise to systems with very sophisticated architectures. A large variety of metal complexes have been formed based on these salt precursors that allowed the preparation of homo and heteroleptic mono-, di- and tri-metal complexes with different geometries. The luminescence properties of various imidazolium salts, the catalytic activity of some of the metal complexes obtained, and host-guest molecular recognition studies have been analyzed.