ChemInform Abstract: Photooxygenation of Alditol-1-C-yl Derivatives of Furan with Singlet Oxygen.
- BANEZ SANZ, J. M. 1
- GALISTEO GONZALEZ, D. 1
- LOPEZ SASTRE, J. A. 1
- RODRIGUEZ AMO, J. F. 1
- ROMERO-AVILA GARCIA, C. 1
- SANTOS GARCIA, M. 1
- SANZ TEJEDOR, M. A. 1
-
1
Universidad de Valladolid
info
ISSN: 0931-7597
Argitalpen urtea: 2010
Alea: 27
Zenbakia: 48
Orrialdeak: no-no
Mota: Artikulua
Beste argitalpen batzuk: ChemInform
Laburpena
Sensitized photooxygenation of fully protected alditol-1-Cylfurans ( cf. (I), (III)) and subsequent reduction of the formed unstable endoperoxide intermediates provides the corresponding chain-extended . alpha.,β-unsaturated aldehydes in high yield. In some cases Z- alkenals like (IV) are formed at first which isomerize spontaneously to the corresponding E-isomer (cf. (V)).
Erreferentzia bibliografikoak
- BANEZ SANZ, (1996), Carbohydr. Res., 289, pp. 179, 10.1016/0008-6215(96)00117-6