ChemInform Abstract: Photooxygenation of Alditol-1-C-yl Derivatives of Furan with Singlet Oxygen.

  1. BANEZ SANZ, J. M. 1
  2. GALISTEO GONZALEZ, D. 1
  3. LOPEZ SASTRE, J. A. 1
  4. RODRIGUEZ AMO, J. F. 1
  5. ROMERO-AVILA GARCIA, C. 1
  6. SANTOS GARCIA, M. 1
  7. SANZ TEJEDOR, M. A. 1
  1. 1 Universidad de Valladolid
    info

    Universidad de Valladolid

    Valladolid, España

    ROR https://ror.org/01fvbaw18

Revista:
ChemInform

ISSN: 0931-7597

Año de publicación: 2010

Volumen: 27

Número: 48

Páginas: no-no

Tipo: Artículo

DOI: 10.1002/CHIN.199648230 GOOGLE SCHOLAR lock_openAcceso abierto editor

Otras publicaciones en: ChemInform

Resumen

Sensitized photooxygenation of fully protected alditol-1-Cylfurans ( cf. (I), (III)) and subsequent reduction of the formed unstable endoperoxide intermediates provides the corresponding chain-extended . alpha.,β-unsaturated aldehydes in high yield. In some cases Z- alkenals like (IV) are formed at first which isomerize spontaneously to the corresponding E-isomer (cf. (V)).

Referencias bibliográficas

  • BANEZ SANZ, (1996), Carbohydr. Res., 289, pp. 179, 10.1016/0008-6215(96)00117-6